We had a model for our oil painting class but only had to stare at her eyes and ears.
I find eyes difficult when in a painting but much easier in isolation like this. The white of the eye is never white, is usually a different shade of grey on one side of the iris from the other due to catching the light at a different angle, is darker in a line under the shade of the eyelid and also darker in the corner of the eyes - so much to think about just for the whites of the eyes.
The iris is surrounded by a dark margin (more pronounced in young people). A "jellybean " of paler iris colour placed opposite the catchlight gives an impression of transparency and the catchlight is never white.
The lower lid is hardly painted at all.
This was a sketchier version.
The tear duct is a warm red.
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